Genesis 4:22

4:22 Now Zillah also gave birth to Tubal-Cain, who heated metal and shaped all kinds of tools made of bronze and iron. The sister of Tubal-Cain was Naamah.

Numbers 31:22

31:22 ‘Only the gold, the silver, the bronze, the iron, the tin, and the lead,

Deuteronomy 8:9

8:9 a land where you may eat food in plenty and find no lack of anything, a land whose stones are iron and from whose hills you can mine copper.

Deuteronomy 8:1

The Lord’s Provision in the Desert

8:1 You must keep carefully all these commandments I am giving you today so that you may live, increase in number, and go in and occupy the land that the Lord promised to your ancestors.

Deuteronomy 22:14

22:14 accusing her of impropriety and defaming her reputation by saying, “I married this woman but when I had sexual relations with her I discovered she was not a virgin!”